SCHEDULED MAINTENANCE
A synthesis of 10-alkynyl-9-allenylanthracenes (and related 10-alkenyl and 10-benzyl analogues)via acid catalysed [3,4]sigmatropic rearrangement of e.g. 10,10-dialkynyl-9-anthranols is reported; the migratory aptitudes of allyl, benzyl, and prop-2-ynyl groups is discussed.
K. C. Majumdar, A. T. Khan and S. K. Chattopadhyay, J. Chem. Soc., Chem. Commun., 1989, 654 DOI: 10.1039/C39890000654
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