Issue 10, 1989

The entropy inhibition of a gas-phase SN2 reaction

Abstract

The observed rate constant for proton transfer is much larger than that for the SN2 gas-phase reaction between protonated methanol and ammonia, which is reproduced reasonably by the theoretical Gibbs free energy change.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 610-612

The entropy inhibition of a gas-phase SN2 reaction

S. Okada, Y. Abe, S. Taniguchi and S. Yamabe, J. Chem. Soc., Chem. Commun., 1989, 610 DOI: 10.1039/C39890000610

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