Reaction between [(η5-C5Me5)RhCl2]2 and [6-(η5-C5Me5)-nido-6-lrB9 H13] in the presence of tetramethylnaphthalenediamine gives the novel isonido eleven-vertex cluster compounds [(η5-C5Me5)2RhHlrB9H10] and [(η5-C5Me5)2RhHlrB9H9Cl] which have quadrilateral open faces with Rh–H–lr and B–H–B bridges.
K. Nestor, X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy and M. Thornton-Pett, J. Chem. Soc., Chem. Commun., 1989, 455 DOI: 10.1039/C39890000455
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