Oxidation of dinaphtho[2,1-d:1′,2′-f][1,3]dithiepine (2) gives a single diastereoisomeric sulphoxide (1) which reacts diastereospecifically with electrophiles at variance with the unoxidized substrate (2) and other combinations of oxides (4),(6), and (7) which afford diastereoisomeric mixtures of products.
G. Delogu, O. De Lucchi and G. Licini, J. Chem. Soc., Chem. Commun., 1989, 411 DOI: 10.1039/C39890000411
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