SCHEDULED MAINTENANCE:
Reaction of Se4N4 with [PtCl2(PMe2Ph)]2, in refluxing CHCl3, results in Pt(Se3N)Cl(PMe2Ph), (1), the first example of a metal selenium–nitrogen complex, which contains the bidentate, selenium-bound Se3N– ligand; from X-ray crystallography (1) is square planar with a bidentate Se3N– ligand co-ordinated through two selenium atoms.
P. F. Kelly, A. M. Z. Slawin, D. J. Williams and J. D. Woollins, J. Chem. Soc., Chem. Commun., 1989, 408 DOI: 10.1039/C39890000408
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