Issue 7, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

Ligand lability in and electron transfer of [Co(py)6]+; cyclotrimerisation of alkynes and synthesis, structure, and properties of (η6-C6Ph6)Co(η2-C2Ph2)(py = pyridine)

Paolo Biagini,   Tiziana Funaioli,   Giuseppe Fachinetti,   Franco Laschi  and  Pier Francesco Zanazzi  

Abstract

In pyridine the ionic CoI complex [Co(py)6][BPh4](py = pyridine) catalyses the cyclotrimerisation of but-2-yne and hex-I-yne at room temperature; under the same conditions, diphenylacetylene promotes an irreversible disproportionation of the CoI complex to give [Co(py)6][BPh4]2 and (η6-C6Ph6)Co(η2-C2Ph2), this compound having been structurally characterised and its reaction with CO investigated.

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Article information

DOI
https://doi.org/10.1039/C39890000405
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 405-407

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Ligand lability in and electron transfer of [Co(py)6]+; cyclotrimerisation of alkynes and synthesis, structure, and properties of (η6-C6Ph6)Co(η2-C2Ph2)(py = pyridine)

P. Biagini, T. Funaioli, G. Fachinetti, F. Laschi and P. F. Zanazzi, J. Chem. Soc., Chem. Commun., 1989, 405 DOI: 10.1039/C39890000405

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