Simplified synthetic models of the bleomycin cobalt complex which contain the AMPHIS {N-[6-(2-aminoethylaminomethyl)pyridin-2-ylcarbonyl]histidine} metal-ion binding ligand and DNA binding component have been prepared; the cobalt complexes cleaved DNA upon photoirradiation.
I. Saito, T. Morii, T. Obayashi, T. Sera, H. Sugiyama and T. Matsuura, J. Chem. Soc., Chem. Commun., 1989, 360 DOI: 10.1039/C39890000360
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