A general method for the synthesis of polymeric binary flurides exemplified by AgF3, NiF4, RuF4, and OsF4
Abstract
Fluride-ion capture from their anion relatives in anhydrous hydrogen fluoride solution by strong fluoride ion acceptors such as AsF5 provides a general approach to the synthesis of polymeric binary fluorides and is particularly advantageous in the synthesis of highest-oxidation-state transition metal polymeric fluorides.