The lithium–magnesium complex [Li(thf)2(µ-Br)2Mg{C(SiMe3)3}thf](thf = tetrahydrofuran) decomposes of heating in vacuum to give [Mg{C(SiMe3)3}2], which is monomeric; this is the first characterisation of a two-co-ordinate magnesium compound in the solid state.
S. S. Al-Juaid, C. Eaborn, P. B. Hitchcock, C. A. McGeary and J. D. Smith, J. Chem. Soc., Chem. Commun., 1989, 273 DOI: 10.1039/C39890000273
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