Cyclohexane-based cis-1,3-dipodand (1) undergoes ring inversion to a diaxial conformation upon Na+ complexation, while related diaxially biased dipodand (2) is a better host.
S. M. Shirodkar and G. R. Weisman, J. Chem. Soc., Chem. Commun., 1989, 236 DOI: 10.1039/C39890000236
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