The reaction of protected 1,2-anhydro sugars with organocuprates provides a new stereocontrolled synthesis of C-glycosides, the deoxygenation of which affords 2-deoxy-C-glycosides in high yield.
V. Bellosta and S. Czernecki, J. Chem. Soc., Chem. Commun., 1989, 199 DOI: 10.1039/C39890000199
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