Primary and secondary kinetic hydrogen isotope effects (k.i.e.s) in the elimination of toluene from the alkoxide of 1,2,3-triphenylpropan-2-ol have been determined and are consistent with rate limiting proton transfer in gas phase reaction and with rate limiting carbon–carbon bond cleavage in reaction in dimethyl sulphoxide (DMSO) solution.
S. Ibrahim, C. I. F. Watt, J. M. Wilson and C. Moore, J. Chem. Soc., Chem. Commun., 1989, 161 DOI: 10.1039/C39890000161
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