Sterically controlled lanthanoid complexes,fac-Λ-tris{4-(/-menthyloxy)-1-(p-tolyl) butane-1,3-dionato}lanthanoid(III), functioned as Lewis acid catalysts for enantioselective reduction of ketones (acetophenone, octan-2-one, butan-2-one) with NaBH4 in cyclohexane.
H. Okawa, T. Katsuki, M. Nakamura, N. Kumagai, Y. Shuin, T. Shinmyozu and S. Kida, J. Chem. Soc., Chem. Commun., 1989, 139 DOI: 10.1039/C39890000139
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