AM1 Calculations indicate that the Cope rearrangement of 3,3-dicyanohexa-1,5-diene takes place by a synchronous pericyclic mechanism involving an aromatic transition state rather than by the biradicaloid path usual in chair Cope rearrangements.
M. J. S. Dewar and C. Jie, J. Chem. Soc., Chem. Commun., 1989, 98 DOI: 10.1039/C39890000098
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