The preparation and physicochemical properties of the new titanium(iv) porphyrin complexes (Por)Ti(Y2) where Y = S or Se and Por = porphyrinato dianion are reported and the structure of the (TpTP)Ti(S2)(TpTP = tetrakis-p-tolylporphyrin) complex has been solved by single crystal X-ray diffraction.
C. Ratti, P. Richard, A. Tabard and R. Guilard, J. Chem. Soc., Chem. Commun., 1989, 69 DOI: 10.1039/C39890000069
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