Deuterium labelling has shown that the isomerisation of E,Z-cyclo-octadiene to the Z,Z-isomer does not occur by a 1,5-hydrogen shift as previously supposed, and thus must occur by a trans-cis rotation.
J. Bramham and C. J. Samuel, J. Chem. Soc., Chem. Commun., 1989, 29 DOI: 10.1039/C39890000029
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