Diastereofacial selection has been shown to occur in the asymmetric intramolecular Diels–Alder reactions of chiral o-quinodimethanes generated by thermal ring-opening of the chiral benzocyclobutenes (1a,b,e,f).
H. Nemoto, M. Nagai, K. Kohzuki, K. Fukumoto and T. Kametani, J. Chem. Soc., Perkin Trans. 1, 1988, 2835 DOI: 10.1039/P19880002835
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