Synthesis of erivanin (2) along with its 1-epimer (17) is reported starting from 1-(α)-santonin, the crucial step in the synthesis being the successful application of Mitsunobu epimerisation procedure on a eudesmanic alcohol (15a) in bringing about inversion of configuration at C-1.
R. S. Harapanhalli, J. Chem. Soc., Perkin Trans. 1, 1988, 2633 DOI: 10.1039/P19880002633
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