Peracid oxidation of 16-arylidene- and 16-alkylidene-5α-androstan-17-ones (1)–(6) gave no α,βunsaturated δ-lactones, but resulted mainly in products of direct oxidation of the olefinic double bond.
L. S. Chagonda and B. A. Marples, J. Chem. Soc., Perkin Trans. 1, 1988, 875 DOI: 10.1039/P19880000875
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