Identification of the absolute stereochemistry of D- and L-oleandroses using a chiral h.p.l.c. column

Abstract

The absolute stereochemistry of D- and L-oleandroses has been determined for the carbamoyl derivatives of the methyl glycosides by h.p.l.c. using a chiral column. The anomeric stereochemistry of methyl α- and β-oleandrofuranosides has also been studied on the basis of nuclear Overhauser effect (n.O.e.) experiments.