The reaction between [V(η-C5Me5)2(CO)] and N2O in toluene at 20 °C gave a mixture of the vanadium(IV) carbonate [V(η-C5Me5)2(CO3)] and a polymer proposed to be [{[{V(η-C5Me5)-(µ-O)}4(OH)2](µ-O)}n]. The reaction is compared with analogous ones of [V(η-C5H5)2(CO)] and [Ti(η-C5R5)2(CO)2](R = H or Me).
F. Bottomley and J. Darkwa, J. Chem. Soc., Dalton Trans., 1988, 2505 DOI: 10.1039/DT9880002505
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