Issue 4, 1988
From the journal:

Journal of the Chemical Society, Dalton Transactions

Notes. Reaction of manganese(II) arsine oxide complexes with sulphur dioxide: some unexpected products. The X-ray crystal structure of [(Ph3AsO)2H]I3

Brian Beagley,   Oraib El-Sayrafi,   George A. Gott,   David G. Kelly,   Charles A. McAuliffe,   Anthony G. Mackie,   Philomena P. MacRory  and  Robin G. Pritchard  

Abstract

The reaction of [Mn(OAsPh3)4I2] with sulphur dioxide in toluene yields [Mn(OAsPh3)3(O2SI)2)]. Two unexpected products, [(Ph3AsO)2H]I3 and [AsPh3I]I3, have been isolated from the reaction filtrate. The molecular structure of [(Ph3AsO)2H]I3 has been determined by single-crystal X-ray diffraction techniques.

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Article information

DOI
https://doi.org/10.1039/DT9880001095
Article type
Paper

J. Chem. Soc., Dalton Trans., 1988, 1095-1097

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Notes. Reaction of manganese(II) arsine oxide complexes with sulphur dioxide: some unexpected products. The X-ray crystal structure of [(Ph3AsO)2H]I3

B. Beagley, O. El-Sayrafi, G. A. Gott, D. G. Kelly, C. A. McAuliffe, A. G. Mackie, P. P. MacRory and R. G. Pritchard, J. Chem. Soc., Dalton Trans., 1988, 1095 DOI: 10.1039/DT9880001095

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