Issue 3, 1988

Reactions of pentafluorophenyl(ylide)-silver(I) or -gold(I) complexes with chlorobis(pentafluorophenyl)thallium(III)

Abstract

Chlorobis(pentafluorophenyl)thallium(III) reacts with silver–ylide complexes [Ag(C6F5)(CH2ER3)](ER3= PPh3, PPh2Me, PPhMe2, or AsPh3) to give AgCl and [Tl(C6F5)3(CH2ER3)], whereas the reactions with gold–ylide complexes, [Au(C6F5)(CH2PR3)], lead to gold(III) complexes of the types trans-[Au(C6F5)2Cl(CH2PR3)] and [Au(CH2PR3)2][Au(C6F5)4] which have been isolated and characterized.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1988, 701-703

Reactions of pentafluorophenyl(ylide)-silver(I) or -gold(I) complexes with chlorobis(pentafluorophenyl)thallium(III)

R. Usón, A. Laguna, M. Laguna, A. Usón and M. C. Gimeno, J. Chem. Soc., Dalton Trans., 1988, 701 DOI: 10.1039/DT9880000701

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements