Darzens condensation of two readily available carbohydrate ketones with chloromethyl p-tolyl sulphone gave stereospecifically α,β-epoxy sulphones, in the presence of azide ion the latter afforded branched-chain functionalized azido-sugars.
T. T. Thang, M. de los A. Laborde, A. Olesker and G. Lukacs, J. Chem. Soc., Chem. Commun., 1988, 1581 DOI: 10.1039/C39880001581
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