Transition metal σ-pentadienyl complexes undergo [4 + 2] and [3 + 2] cycloadditions and insertion reactions with dienophiles, depending on the type of dienyl ligand and dienophile.
G. Lee, S. Peng, S. Lush and R. Liu, J. Chem. Soc., Chem. Commun., 1988, 1513 DOI: 10.1039/C39880001513
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