Complexes [Rh(HBPz*3)(CO)(η2-alkene)](Pz*= 3,5-dimethylpyrazol-1-yl) lose alkene at 70–100 °C in benzene solution forming [Rh(HBPz*3)(H)(Ph)(CO)] in high yield; the equilibrium constant for the reaction with alkene = cyclo-octene is 0.016 at 100 °C.
C. K. Ghosh, D. P. S. Rodgers and W. A. G. Graham, J. Chem. Soc., Chem. Commun., 1988, 1511 DOI: 10.1039/C39880001511
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