In contrast with ester cations (RCO2R) which rearrange spontaneously at 77 K via intramolecular hydrogen atom transfer, stable π-radical cations of ethyl dithioacetate (MeCSSEt+˙) have been observed by e.s.r. spectroscopy, following γ-irradiation of dilute frozen solutions in CFCl3 at 77 K.
C. J. Rhodes, J. Chem. Soc., Chem. Commun., 1988, 1477 DOI: 10.1039/C39880001477
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