A 4Fe–4S cluster with the 1-adamantanethiolate (SAd) ligand, (Et4N)2[Fe4S4(SAd)4], has been prepared as the first synthetic analogue of high potential iron–sulphur proteins (HiPIP), and shows the [Fe4S4]2+/3+ redox couple both in dimethylformamide and in aqueous solution.
M. Nakamoto, K. Tanaka and T. Tanaka, J. Chem. Soc., Chem. Commun., 1988, 1422 DOI: 10.1039/C39880001422
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