Issue 20, 1988

Novel metallacycle formation in the reaction of carbon dioxide with the rhodium complex mer-[HRh(CH2COMe)(PMe3)3Cl]

Abstract

The title compound (1) reacts with CO2, apparently reversibly, to form [Rh(CH2CHMeOCO2)(PMe3)3Cl](2), the structure of which has been established by X-ray diffraction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1384-1385

Novel metallacycle formation in the reaction of carbon dioxide with the rhodium complex mer-[HRh(CH2COMe)(PMe3)3Cl]

M. Farmer, M. A. Khan and K. M. Nicholas, J. Chem. Soc., Chem. Commun., 1988, 1384 DOI: 10.1039/C39880001384

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