A new and stereospecific synthesis for conduritol-A has been developed starting from cyclohexa-1,4-diene where hydroxy groups have been introduced by classical KMnO4-oxidation followed by photo-oxygenation; suitable ring-opening reactions gave the desired conduritol-A.
Y. Sütbeyaz, H. Seçen and M. Balci, J. Chem. Soc., Chem. Commun., 1988, 1330 DOI: 10.1039/C39880001330
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