Phenylthio and hydroxymethyl groups may be introduced into nitroalkenes stereoselectively by treatment with benzenethiol and aqueous formaldehyde to give anti-γ-phenylthio-β-nitro alcohols, which are converted into (E)-allyl alcohols via radical elimination induced by Bu3SnH.
A. Kamimura and N. Ono, J. Chem. Soc., Chem. Commun., 1988, 1278 DOI: 10.1039/C39880001278
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