Issue 18, 1988

Electrochemical detection of the Cr(CO)3(MeCN)3+ intermediate in the one-electron oxidation of arene- and thiophene-chromiumtricarbonyl complexes

Abstract

Oxidation of LCr(CO)3, (L = C6H6, C6H5Cl, dimethylaniline, thiophene, 3-methylthiophene) in acetonitrile leads to a rapid follow-up reaction in which the intermediate Cr(CO)3(MeCN)3+ is detected by cyclic voltammetry.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1264-1266

Electrochemical detection of the Cr(CO)3(MeCN)3+ intermediate in the one-electron oxidation of arene- and thiophene-chromiumtricarbonyl complexes

F. Rourke and J. A. Crayston, J. Chem. Soc., Chem. Commun., 1988, 1264 DOI: 10.1039/C39880001264

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