Mixed-valence di-µ-oxo complexes of the form [LMnO]2(ClO4)3(L = 1,4,8,11-tetra-azacyclotetradecane or 1,4,7,10-tetra-azacyclododecane) have been synthesized; their electrochemical properties in 1.5% water–acetonitrile indicate that the oxidized forms interact with water.
K. J. Brewer, A. Liegeois, J. W. Otvos, M. Calvin and L. O. Spreer, J. Chem. Soc., Chem. Commun., 1988, 1219 DOI: 10.1039/C39880001219
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