Strong 15N nuclear polarisation is present in both the uncatalysed and acid-catalysed rearrangements of 4-methyl-4-nitrocyclohexa-2,5-dienone but is absent from the rearrangement of 2-methyl-2-nitrocyclohexa-3,5-dienone.
J. H. Ridd, J. P. B. Sandall and S. Trevellick, J. Chem. Soc., Chem. Commun., 1988, 1195 DOI: 10.1039/C39880001195
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