The intramolecular Diels–Alder reaction of the C15 tetraene (6) prepared by attachment of a long-chain alkyl group with a terminal double bond to 2,5-dihydro-3-methyl thiophene S,S-dioxide, followed by extrusion of SO2, has been employed in an efficient total synthesis of selina-3,7(11)-diene.
S. Lee and T. Chou, J. Chem. Soc., Chem. Commun., 1988, 1188 DOI: 10.1039/C39880001188
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