Issue 16, 1988

An alternative synthetic route to 3H-azepines: thermal isomerization of 2,4-and 3,5-di-t-butyl-3a,5a-dihydro-3H-cyclobuta[b]pyrroles

Abstract

Di-t-butyl derivatives of 3a,5a-dihydro-3H-cyclobuta[b]pyrroles, synthesized from photoisomers of 1H-azepine derivatives (Dewar azepines), isomerized thermally to 3H-azepines.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1121-1123

An alternative synthetic route to 3H-azepines: thermal isomerization of 2,4-and 3,5-di-t-butyl-3a,5a-dihydro-3H-cyclobuta[b]pyrroles

K. Satake, H. Saitoh, M. Kimura and S. Morosawa, J. Chem. Soc., Chem. Commun., 1988, 1121 DOI: 10.1039/C39880001121

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