Issue 16, 1988

E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH2CH2CH[double bond, length half m-dash]NH2

Abstract

The radical cation formed by radiolytic oxidation of prop-2-enylamine (allylamine) in Freon matrices at 77 K is the 3-iminiopropyl distonic species (3-iminium-1-propyl radical) resulting from a 1,2-hydrogen shift in the parent cation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1069-1071

E.s.r. evidence for the rearrangement at 77 K of ionized allylamine to the distonic radical cation ·CH2CH2CH[double bond, length half m-dash]NH2

S. Dai, Q. Guo, J. T. Wang and F. Williams, J. Chem. Soc., Chem. Commun., 1988, 1069 DOI: 10.1039/C39880001069

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