Conjugated trienes have been synthesised readily and stereoselectively by the coupling reaction of 2-tri-n-butylstannyl-2,5-dihydrothiophene S,S-dioxides with vinyl iodides in the presence of tetrakis(triphenylphosphine)palladium(0), followed by desulphonylation.
H. Takayama and T. Suzuki, J. Chem. Soc., Chem. Commun., 1988, 1044 DOI: 10.1039/C39880001044
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