Reaction of [(PMe3)3RhCl] with pent-4-ynoic acid yields the novel exocyclic methylene-substituted rhoda-lactone [(PMe3)3Cl[graphic ommitted]], which reacts with Me3O+BF4– to give [(PMe3)3ClR[graphic ommitted]]BF4; both complexes have been structurally characterized.
T. B. Marder, D. M.-T. Chan, W. C. Fultz and D. Milstein, J. Chem. Soc., Chem. Commun., 1988, 996 DOI: 10.1039/C39880000996
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