Issue 14, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4]

David N. Cox  and  Raymond Roulet  

Abstract

Chloride extraction from [Ru(η3 : η3-C10H16)Cl2]2 or [Ru(η3 : η3-C10H16)Cl2L][L = P(OMe)3 or ButNC], in the presence of diolefins, results in labilisation of the 2,7-dimethyloctadienediyl ligand and provides syntheses of some new organoruthenium complexes, including the protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4].

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Article information

DOI
https://doi.org/10.1039/C39880000951
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 951-953

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Octadienediyl dichlorides of ruthenium(IV) as synthetic reagents in organoruthenium chemistry; isolation of a protonated ‘open metallocene’[Ru(η5-C7H11)2H][BF4]

D. N. Cox and R. Roulet, J. Chem. Soc., Chem. Commun., 1988, 951 DOI: 10.1039/C39880000951

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