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An X-ray structural analysis of the title charge-transfer complex revealed an unusual cage-like network formed by S––N![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
C interactions of bis[1,2,5]thiadiazolotetracyanoquinodimethane (BTDA)(1) in which benzene was tightly included; the stabilization observed may be attributed to this inclusion behaviour.
T. Suzuki, C. Kabuto, Y. Yamashita, T. Mukai and T. Miyashi, J. Chem. Soc., Chem. Commun., 1988, 895 DOI: 10.1039/C39880000895
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