Issue 13, 1988

Preparation of 5H-1,4,2-dithiazoles via 1,3-dipolar cycloadditions of nitrile sulphides to thiocarbonyl compounds; the first synthesis of a 3,5-diaryl-1,4,2-dithiazolium salt

Abstract

Nitrile sulphides from the thermal decomposition of 1,3,4-oxathiazol-2-ones add to thiocarbonyl compounds giving moderate to high yields of 5H-1,4,2-dithiazoles; an adduct from O-ethyl thiobenzoate has been converted into 3-(4-nitrophenyl)-5-phenyl-1,4,2-dithiazolium tetrafluoroborate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 852-853

Preparation of 5H-1,4,2-dithiazoles via 1,3-dipolar cycloadditions of nitrile sulphides to thiocarbonyl compounds; the first synthesis of a 3,5-diaryl-1,4,2-dithiazolium salt

K. Wai and M. P. Sammes, J. Chem. Soc., Chem. Commun., 1988, 852 DOI: 10.1039/C39880000852

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