Issue 11, 1988

Novel ligand effect on cobalt(III) complex promoted hydrolysis of a phosphate diester

Abstract

Bis-p-nitrophenyl phosphate when bound to the cobalt(III) complex [(trpn)Co(OH)(OH2)][trpn = tris-(3-aminopropyl)amine] is hydrolysed about three hundred times more rapidly than when bound to [(tren)Co(OH)(OH2)][tren = tris-(2-aminoethyl)amine], and ca. ten billion times more rapidly than the free phosphate diester.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 735-736

Novel ligand effect on cobalt(III) complex promoted hydrolysis of a phosphate diester

J. Chin, M. Banaszczyk and V. Jubian, J. Chem. Soc., Chem. Commun., 1988, 735 DOI: 10.1039/C39880000735

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