Issue 9, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Carbon–carbon triple bond cleavage at room temperature with nonacarbonyldi-iron: synthesis of [Fe3(CO)9(µ3-CMe)(µ3-CNEt2)]

E. Cabrera,   J. C. Daran  and  Yves Jeannin  

Abstract

An aminoalkyne C[triple bond, length half m-dash]C triple bond has been cleaved at room temperature in the presence of [Fe2(CO)9] using a sodium diphenylketyl catalyst; a di-µ3-carbyne cluster is formed.

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Article information

DOI
https://doi.org/10.1039/C39880000607
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 607-608

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Carbon–carbon triple bond cleavage at room temperature with nonacarbonyldi-iron: synthesis of [Fe3(CO)9(µ3-CMe)(µ3-CNEt2)]

E. Cabrera, J. C. Daran and Y. Jeannin, J. Chem. Soc., Chem. Commun., 1988, 607 DOI: 10.1039/C39880000607

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