Anomalous hydrolysis behaviour of [n.n] paracyclophanediazonium salts: a new route to bridged benzobarrelenes
Abstract
The hydrolysis of diazotized 5-amino-[3.3]paracyclophane and anti-4-amino[2.2](1,4)naphthalenoparacyclophane gives products having a barrelene structure, presumably via an aryne mechanism.
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