Acid-catalysed nitrosation of methanol, thioglycolic acid, and water in acetonitrile using alkyl nitrites or nitrous acid (except in the case of water), is kinetically zero order in the substrate, consistent with rate-limiting NO+ formation.
M. J. Crookes and D. L. H. Williams, J. Chem. Soc., Chem. Commun., 1988, 571 DOI: 10.1039/C39880000571
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