Issue 8, 1988

An unexpected ring opening–ring closure reaction of 5-azido-4-formylpyrazole

Abstract

5-Chloro-4-formyl-1-methylpyrazoles give 1-azidomethyl-4-cyanopyrazoles on reaction with an excess of sodium azide in dimethyl sulphoxide (DMSO), as a result of a ring opening–ring closure reaction; the crystal structure of the azidomethylpyrazole has been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 541-542

An unexpected ring opening–ring closure reaction of 5-azido-4-formylpyrazole

J. Becher, K. Brøndum, N. Krake, K. Pluta, O. Simonsen, P. Molina and M. Begtrup, J. Chem. Soc., Chem. Commun., 1988, 541 DOI: 10.1039/C39880000541

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