A straightforward route from D-glucose to conjugated enal and diene pyranoses through a dithiane-based methodology is disclosed; hetero Diels–Alder reaction of the enals with ethyl vinyl ether occurs with high stereoselectivity.
J. C. Lopez, E. Lameignere and G. Lukacs, J. Chem. Soc., Chem. Commun., 1988, 514 DOI: 10.1039/C39880000514
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