NaY zeolite encapsulated Rh6 clusters characterized by EXAFS and Fourier transform i.r. spectroscopy led to the selective formation of C2–C4 alkenes in the reaction of CO + H2 under atmospheric pressure, whereas RhFe carbonyl clusters synthesized in NaY showed a unique activity for formation of a mixture of ethanol and methanol.
L. Rao, A. Fukuoka and M. Ichikawa, J. Chem. Soc., Chem. Commun., 1988, 458 DOI: 10.1039/C39880000458
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