Issue 6, 1988

Synthesis of naucléfine, angustidine, angustine, and (±)-13b, 14-dihydroangustine

Abstract

2,9-Bis-(trimethylsilyl)-3,4-dihydropyrido[3,4-b]indolium trifluoromethanesulphonate reacts with the lithio derivatives of 3-cyano-4-methylpyridines to generate pentacyclic amidines which, upon hydrolysis and oxidation, produce naucléfine, angustine, and angustidine.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 439-440

Synthesis of naucléfine, angustidine, angustine, and (±)-13b, 14-dihydroangustine

D. B. Repke, Jahangir, R. D. Clark and D. B. MacLean, J. Chem. Soc., Chem. Commun., 1988, 439 DOI: 10.1039/C39880000439

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